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Time-resolved infrared spectroscopy, offering both temporal and spectral resolution in the experimental measurements, plays an important role in atmospheric, biological, and chemical physics studies. Dual-comb spectroscopy, a multi-heterodyne Fourier transform spectroscopy based on two frequency combs at slightly different repetition frequencies, enables broadband molecular fingerprinting with high-resolution and fast spectral acquisition. Here, a new approach for high-resolution time-resolved spectroscopy using mid-infrared dual-comb spectrometers will be reported. The time-resolved dual-comb spectra under different experimental conditions can be measured with Doppler-limited resolution at microsecond time resolution. Moreover, employing the dual-comb spectrometers coupled with a flash photolysis cell, multiple species, including the free radicals and reaction intermediates can be simultaneously and quantitatively detected, thus enabling to explore complex reaction processes and mechanisms. Our recent works on the study of the yields and formation mechanisms of OH and HO2 radicals in the reactions involving the Criegee intermediates, short-lived species involved in many key atmospheric reactions, will be presented in this talk. The approach with time-resolved dual-comb spectroscopy holds promise not only in exploring the issues of chemical physics but also in discovering transient processes of light-matter interactions in different fields.